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Investigating Bay-Substituted 6,7-Dihydrodibenzo[b,j][4,7]phenanthroline, a Class of Tunable Hindered Rotors: Synthesis and Molecular Dynamics J. Org. Chem. (IF 3.3) Pub Date : 2025-06-03
Yen-Cheng Lu, Jhih-Syong Jhang, Chih-Hsiu Lin -
1,3,4-Oxadiazole-Bridged 3,5-Dinitropyrazoles: Powerful Alliance toward High Performance and High Thermal Stability J. Org. Chem. (IF 3.3) Pub Date : 2025-06-03
Krishna Pandey, Priyanka Das, Amit Bijlwan, Dheeraj Kumar -
Multicomponent Synthesis of 3-Thiazolines Using a Modified Asinger-Type Reaction J. Org. Chem. (IF 3.3) Pub Date : 2025-06-03
Vincent R.A.M. Reinartz, Jordy M. Saya, Darya Hadavi, Jules A.W. Harings, Romano V.A. Orrù -
Total Synthesis of Labile Antibacterial Polyketide Thailandamide A and a More Stable but Equally Potent Morpholine Amide Derivative J. Org. Chem. (IF 3.3) Pub Date : 2025-06-03
Himangshu Sharma, Nasif Ali, Swapnamoy Ganguly, Suparno Banerjee, Ritesh Ranjan Pal, Rajib Kumar Goswami -
[2 + 2] Photocycloadditions of Conformationally Constrained Styrenes Enabled by Triplet Lifetime Extension J. Org. Chem. (IF 3.3) Pub Date : 2025-06-03
Christina Cong, Nicholas J. Fastuca, Alberto Castanedo, Peter R. Meinig, Bradford C. Woodger, Lingbowei Hu, Farid W. van der Mei, Philip R. D. Murray, Geraint H. M. Davies, Jillian Zoglio, Laura Akullian D’Agostino, Robert R. Knowles -
Fissistonones A and B: Two Phenylpropanoyl Prenylated Naphthoquinones with Rearranged Carbon Skeletons from Fissistigma oldhamii J. Org. Chem. (IF 3.3) Pub Date : 2025-06-03
Chu-Hua Lai, Jun-Cheng Su, Hai-Wang Yang, Yun-Qi Fan, Jian-Guo Song, Ni-Ping Li, Wen-Tao Wei, Yang Chen, Lei Wang, Ji-Hong Gu -
C–N Atropisomerism and Anti-MRSA Activity in 3-(2-Hydroxyphenyl)quinazolin-4-one Derivatives J. Org. Chem. (IF 3.3) Pub Date : 2025-06-03
Yuxiang Wang, Hiroshi Kaneko, Yue Yang, Saki Komamatsu, Kosuke Nakamura, Azusa Sato, Hikaru Yanai, Hidemasa Nakaminami, Osamu Kitagawa -
Decarboxylative C-Terminus Amidation of Amino Acids and Peptides in the Presence of Isocyanates J. Org. Chem. (IF 3.3) Pub Date : 2025-06-02
Aman Singh Barahdia, Karuna Thakare, Rahul Jain -
Rearrangement and Cyclization of Enamine Thianthrenium Salts: Effective Access to Substituted Indoles J. Org. Chem. (IF 3.3) Pub Date : 2025-06-02
Zhixin Ren, Chengli Deng, Zi-Jing Bai, Wei Shi, Peng Gao -
Pyromellitic Diimide-Extended Resorcin[6]arene: Synthesis, Structure, and Iodine Adsorption J. Org. Chem. (IF 3.3) Pub Date : 2025-06-02
Jing Zeng, Wan-Xia Liu, Man-Hua Ding, Lin-Li Tang, Ying-Zi Tan, Fei Zeng -
Metal-Free Electrophilic Phosphination with Soft Carbon Nucleophiles: Access to Diverse β-Ketophosphine Oxides J. Org. Chem. (IF 3.3) Pub Date : 2025-06-02
Da-Wei Shi, Ming Li, Zhi-Chao Wang, Jie Liu, Ying-Hao Xin, Jun-Ru Liu, Shang-Dong Yang, Bin Yang -
B/Cu Synergistic Catalysis for the Asymmetric Mannich Reaction between β,γ-Alkynyl-α-ketimino Esters and Ortho-Hydroxy Aryl Ketones J. Org. Chem. (IF 3.3) Pub Date : 2025-06-02
Jiani Sun, Changwen Yan, Qiao Wang, Wen Wan, Xiaoyu Wu -
Symmetric and Unsymmetric Bifurcating Surfaces of Ambimodal Reactions: Origin of Electronic Behavior in Post-Transition State Bifurcation J. Org. Chem. (IF 3.3) Pub Date : 2025-06-02
Rama Krishna Kadiyam, Akanksha Ashok Sangolkar, Ravinder Pawar -
2,2′-Bibenzimidazole-Based Hyper-Cross-Linked Polymer Supported-Iridium Complex: A Recyclable Metal–Polymer Ligand Bifunctional Catalyst for the α-Methylation of Arylacetonitriles with Methanol J. Org. Chem. (IF 3.3) Pub Date : 2025-06-02
Deyun Liu, Xiaozhong Chen, Beixuan Dong, Yuexin Ji, Junjie Yu, Shouhai Zhang, Feng Li -
Slice-Selective NMR for Quantitative Analysis of Liquid–Liquid Biphasic Systems: A Tool for Organic Chemists J. Org. Chem. (IF 3.3) Pub Date : 2025-06-02
Yael Ben-Tal, Jason E. Hein -
Construction of 2,3-Naphthalimides through Cu-Catalyzed Decarboxylative Coupling between Arylpropiolic Acids and Isocyanides J. Org. Chem. (IF 3.3) Pub Date : 2025-06-02
Monty Kumar, Prashant Kumar, Ruchir Kant, Ajay Kumar Srivastava -
Bioinspired Syntheses of Seven Macrodiolide Analogs of Aplysiatoxin by the Late-Stage Functionalization of a Dehydroaplysiatoxin Derivative J. Org. Chem. (IF 3.3) Pub Date : 2025-06-01
Kohei Hada, Toshio Nishikawa -
Electrochemical Oxidation of Primary Amines for the Synthesis of Benzimidazole, Benzothiazole, Quinazolinone, and Quinoxaline J. Org. Chem. (IF 3.3) Pub Date : 2025-06-01
Jiayi Zou, Jundong Xu, Lijun Li, Zan Yang, Congshan Zhou -
Cobalt-Catalyzed anti-Markovnikov-Selective Hydroborylation of Perfluoroalkylethylenes J. Org. Chem. (IF 3.3) Pub Date : 2025-05-31
Renning Dong, Yangjie Huang, Liqin Wei, Lili Xie, Zhiqiang Weng -
Two-Step Benzo[e]indole Core Assemblage from Three 1H-1,2,3-Triazole Molecules via “Transannulation/C–H Insertion/SEAr–Cyclization” Sequence J. Org. Chem. (IF 3.3) Pub Date : 2025-05-31
Ivan V. Simdianov, Pavel A. Sakharov, Alexander F. Khlebnikov, Maksim E. Luginin, Elena V. Grachova, Mikhail S. Novikov -
Reactivity Tuning for Selective Aldimino-Sulfonylation of Styrenes by Photocatalytic Activation of Sulfonyl Aldimines J. Org. Chem. (IF 3.3) Pub Date : 2025-05-31
Jia Huang, Nuerzhati Nuermaimaiti, Qiuping Ding, Yong Luo -
Site-Selective C(sp3)–H Fluorination of Saccharides: Switching the Reaction Sites by Changing Fluorination Reagents and Hydrogen Atom Transfer Catalysts J. Org. Chem. (IF 3.3) Pub Date : 2025-05-31
Erina Kurokawa, Yanru Li, Sakura Okuyama, Kohei Sekine, Yoichiro Kuninobu -
Direct Hydrodecarboxylation of Carboxylic Acids via N-Hydroxyphthalimide-Mediated Hydrogen Atom Transfer J. Org. Chem. (IF 3.3) Pub Date : 2025-05-31
Si-Yu Gao, Yi-Yang Tang, Lan Yang, Peng-Lin Zhang -
Insertion of Arynes into the C–C σ-Bond of α-Pentafluorosulfanyl Ketones: Access to 2-(Pentafluorosulfanyl)methyl Benzophenones J. Org. Chem. (IF 3.3) Pub Date : 2025-05-30
Zeguo Fang, Jia-Yi Shou, Md Nuruzzaman Khan, Xu-Biao He, Xin Jia, Feng-Ling Qing -
Mechanistic and Thermodynamic Studies on Copper-Catalyzed Directing Group-Assisted C-4/C-8 Amination of Aryl Amines with Cyclic Amines J. Org. Chem. (IF 3.3) Pub Date : 2025-05-30
Jinglei Cui, Wenrui Zheng, Qianxi Zhang, Hao Jin, Mengtong Shi -
Assembly of C-Alkyl Glycosides by Pd/NBE-Catalyzed 1,2-Functionalization of Glycals J. Org. Chem. (IF 3.3) Pub Date : 2025-05-30
Penggang Zhao, Qirui Yin, Muhammad Nasir Siddique, Lili Li, Yingpeng Su, Xiaolei Wang -
Rise of Ketone α-Hydrolysis: Revisiting SNAcyl, E1cB Mechanisms and Carbon-Based Leaving Groups in One Reaction for Drug-Targeting Applications J. Org. Chem. (IF 3.3) Pub Date : 2025-05-30
Raed M. Maklad, Islam S. Marae, Omaima F. Ibrahim, Shaaban K. Mohamed, Etify A. Bakhite, Walid Sharmoukh -
Temperature-Dependent, Switchable Synthesis of α-Carbolines and Tetrahydropyrrolo[2,3-b]indoles via Formal [4 + 1 + 1] and [3 + 1 + 1] Cyclizations J. Org. Chem. (IF 3.3) Pub Date : 2025-05-30
Siyang Xing, Lvrong Jin, Fangfang Jing, Xiqing Wang, Jingyu Pang, Bolin Zhu -
Synthesis of Unsaturated 1,6-Diketones and 1,6-Diols from Muconic Acid J. Org. Chem. (IF 3.3) Pub Date : 2025-05-29
Andrey I. Puzanov, Dmitriy N. Zakusilo, Irina A. Boyarskaya, Alexander Yu. Ivanov, Dar’ya V. Spiridonova, Mariya A. Kryukova, Aleksander V. Vasilyev -
Access to Terminal Alkynes via Palladium-Catalyzed Coupling of ArCl with a Low Catalyst Loading of 0.08 mol % J. Org. Chem. (IF 3.3) Pub Date : 2025-05-29
Lei Xu, Gen-Qiang Chen, Xumu Zhang -
Development of Multidentate P,P,N,N-Ligands for Ruthenium-Catalyzed Enantioselective Hydrogenation of 2-Pyridyl Ketones J. Org. Chem. (IF 3.3) Pub Date : 2025-05-29
Lei Xu, Hao Sun, Xuefeng Tan, Dong Li, Gen-Qiang Chen, Xumu Zhang -
Base-Mediated Cyclization of N-Benzyl Ketimines with Vinyl Sulfoxides: An Approach to Polysubstituted 1-Pyrrolines J. Org. Chem. (IF 3.3) Pub Date : 2025-05-29
Tenglong Xu, Donghao Wang, Zhen Liang, Yi Chen, Zimei Zhong, Min Wang, Aifang WangA protocol for synthesizing polysubstituted 1-pyrrolines (3,4-dihydro-2H-pyrrole) via base-mediated [3 + 2] cycloaddition of vinyl sulfoxides with N-benzyl ketimines under mild conditions has been developed. The methodology exhibits exceptional functional group compatibility, demonstrating applicability to both terminal and internal vinyl sulfoxide substrates. Control experiments and 1H NMR analyses
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Tandem Phosphorodithiolation/Rearrangement of Allylic Alcohols with P4S10 and Alcohols to Construct Allylic Phosphorodithioates J. Org. Chem. (IF 3.3) Pub Date : 2025-05-29
Jian Huang, Yingjie Wang, Yufen Lv, Xiaohui Zhao, Zu-Li Wang, Wei Wei, Dong Yi -
Iridium(III)-Catalyzed Cyclization of Oximes with Iodonium Ylides: Synthesis of Multisubstituted Heterocyclic N-Oxides J. Org. Chem. (IF 3.3) Pub Date : 2025-05-29
Narasingan Aravindan, Masilamani Jeganmohan -
De Novo Syntheses of Coumaronochromones: Application in Total Synthesis of Cristatone II J. Org. Chem. (IF 3.3) Pub Date : 2025-05-29
Shao-Tao Yuan, Yan-Ping Peng, Dan Xia, Jing Jiang, Kun Li, Dashan Li, Wen-Jing Wang, Cai-Xian Yan, Li-Dong Shao -
TiCl4-Mediated Diastereoselective Tandem Reactions of Functionalized Keto Esters and Dihydrofurans: Synthesis of Substituted Tricyclic Hexahydro-2H-benzocycloheptafurans J. Org. Chem. (IF 3.3) Pub Date : 2025-05-29
Arun K. Ghosh, Tristan John McDonald, Nilanjana Chakraborty -
Cocrystal of Configurational/Conformational Isomers in Energetic Materials: Binitroaminofurazan with a 1,2,4,5-Tetrazine Bridge J. Org. Chem. (IF 3.3) Pub Date : 2025-05-29
Wentong Tu, Linyuan Wen, Kunkai Wang, Yingzhe Liu, Zhixiang Xie -
Selective Synthesis of Z-α-Iodostyrenes via Hydroiodination and Photochemical Manganese-Catalyzed Geometric Isomerization J. Org. Chem. (IF 3.3) Pub Date : 2025-05-29
Ya-Jie Tang, Qi Fan, Shuang Lin, Qingjiang Li, Biaolin Yin, Honggen Wang -
Vanadium-Catalyzed Trifluoromethylation/Cyclization of Alkenes and 1,7-Enynes with Togni-II Reagent to Access Trifluoromethylated Oxindoles, Isoquinoline-1,3-diones, and Indeno[1,2-c]quinolines J. Org. Chem. (IF 3.3) Pub Date : 2025-05-28
Lei Zhang, Mengdi Liu, Jinjin Zhao, Shaodan Li -
Deconstruction of Desacetamidocolchicine’s B Ring Reveals a Class 3 Atropisomeric AC Ring with Tubulin Binding Properties J. Org. Chem. (IF 3.3) Pub Date : 2025-05-27
Lauren P. Bejcek, Orugbani S. Eli, Diana M. Kapkayeva, Jordan Nafie, John A. Beutler, Emilio Gallicchio, Dan L. Sackett, Ryan P. Murelli -
Development of New Indole-Based N-Heterocyclic Carbene Copper Complexes and Their Applications in Catalysis J. Org. Chem. (IF 3.3) Pub Date : 2025-05-28
Chun-Fa Lin, Ya-Hsuan Tseng, Hui-Yu Hsieh, Pei-Jei Hung, Yan-Wen Huang, Dong-Sheng Lee, Ta-Jung Lu -
Z-Selective Semihydrogenation of Electron-Deficient Alkynes Using Cu(dppf)(BH4) as the Hydrogen Donor J. Org. Chem. (IF 3.3) Pub Date : 2025-05-28
Jin Zhou, Jinhui Hu, Zhihao Zhang, Chengcheng Xia, Zhiyong Yang, Qinzhen Li, Chenlu Xie, Bei Zhang, Manzhou Zhu -
Synthesis of Octatrimethylsilyl-[8]cycloparaphenylene for Multifunctionalized Cycloparaphenylene J. Org. Chem. (IF 3.3) Pub Date : 2025-05-28
Yu Ren, Wansong Shang, Haoran Sun, Qi Liang, Eiichi Kayahara, Shigeru Yamago, Yanbang Li, Deqing Zhang -
Cobalt-Catalyzed Cascade Synthesis of 5-Amino-1,2,4-triazolo[1,5-c]quinazoline Derivatives via Multiple C–N Bonds Construction J. Org. Chem. (IF 3.3) Pub Date : 2025-05-28
Zhengkun Li, Shen-Xun Wu, You Zi, Shun-Jun Ji, Xiao-Ping Xu -
Total Synthesis of (+)-Paucidactine D J. Org. Chem. (IF 3.3) Pub Date : 2025-05-28
Austin H. Asari, Dale L. Boger -
Synthesis of Imidazo[2,1-a]isoindolones via Rearrangement and Tandem Cyclization of Amino-Acid-Based N-Phenacyl-2-cyano-4-nitrobenzensulfonamides J. Org. Chem. (IF 3.3) Pub Date : 2025-05-27
Barbora Lemrová, Kateřina Žáková, Miroslav Soural -
Chemoselective N1 or C3 Cyclization Reaction of Indoles with Tetrasubstituted Olefins: Diastereoselective Synthesis of Pyrroloindoles or Cyclopenta[b]indoles Tethered with Seven-Membered Rings J. Org. Chem. (IF 3.3) Pub Date : 2025-05-27
Zongkang Wang, Lan Tu, Ziyi Zhuang, Yan Wang, Nana Fei, Peng He, Lingkai Kong, Yanzhong Li -
In Search of Radical Transformations from Metal Enolates. Direct Reactions of N-Acyl-1,3-oxazolidin-2-ones with TEMPO Catalyzed by Copper(II) Acetate J. Org. Chem. (IF 3.3) Pub Date : 2025-05-27
Eduard Balaguer-Garcia, Marina Pérez-Palau, Cristina Bello, Anna Maria Costa, Pedro Romea, Fèlix Urpí -
Protective Group-Dependent Iridium-Catalyzed CH Borylations of Levodopa J. Org. Chem. (IF 3.3) Pub Date : 2025-05-27
Cliff Yang, Jinda Fan, Robert E. Maleczka, Jr. -
Nucleophilic Substitution of 1,3-Diiodobicyclo[1.1.1]pentane: Synthesis of Bicyclo[1.1.1]pentylpyridinium, Quinolinium, Isoquinolinium, and Pyrazolium Salts J. Org. Chem. (IF 3.3) Pub Date : 2025-05-27
Harvey J. C. Monroe, Dolapo J. Bello, Bradley J. Duff, Mark R. J. Elsegood, Kohei Watanabe, Gareth J. Pritchard, Marc C. Kimber -
Easy Access to α,β-Diamino-Substituted Cyclopentenaminones through Copper-Catalyzed Double Amination of Unactivated Cyclic Ketones J. Org. Chem. (IF 3.3) Pub Date : 2025-05-27
Yihan Wang, Xiaojuan Yang, Zhiying Zhang, Xiaofeng Hua, Yinyun Lin, Peiyi Chen, Xiaoqing Zhu, Wei Guo, Lvyin Zheng -
Photoinduced Nickel-Mediated Radical Coupling Reaction of Sodium Sulfinates with N-Hydroxyphthalimide Esters J. Org. Chem. (IF 3.3) Pub Date : 2025-05-27
Linze Zheng, Longyu Wang, Muliang Zhang, Shi-Kai Tian -
Synthesis of 1,2,3-Triazoles and Pyridazines from N-Tosylhydrazones J. Org. Chem. (IF 3.3) Pub Date : 2025-05-26
Wentao Yu, Qian Zhang, Fengli An, Meng Tang -
Solvent Effects in Boronic Acid-Diol Binding J. Org. Chem. (IF 3.3) Pub Date : 2025-05-26
Aidan M. Comiskey, Eric V. Anslyn -
Synthesis of Highly Dipolar, Zwitterionic Naphthalene Diimides: Access to Stable, Six-State Amphoteric-Redox Property, and Large NLO Response J. Org. Chem. (IF 3.3) Pub Date : 2025-05-26
Sudhir Kumar Keshri, Bidhan Hazra, Yogendra Kumar, Mrigank Singh Verma, Manabendra Chandra, Pritam Mukhopadhyay -
C(sp3)–H Oxidation of Spiroguanidine-Containing Cyclopentanes J. Org. Chem. (IF 3.3) Pub Date : 2025-05-26
Yuki Kimura, Sangita Karanjit, Ryota Sato, Kosuke Namba -
Access to Unsymmetric m-Terphenyl Derivatives via Ligand-Promoted Pd-Catalyzed Remote meta-C–H Arylation J. Org. Chem. (IF 3.3) Pub Date : 2025-05-25
Xu Yang, Hai Liu, Yao-Dong Li, Jie Wang, Hua-Jin Xu, Yi Hu -
Markovnikov Protoborylation of Unactivated Terminal Alkenes via Copper-Guanidine Catalysis J. Org. Chem. (IF 3.3) Pub Date : 2025-05-23
Tao Jin, Yicen Ge, Ai Zhang, Lin Ge, Huangfeng Zhang, Siyu Jiang, Jian Chen, Xiaoyan Ma, Jinghua Tang, Jinyu Liu -
Time-Reduced N-Methylation: Exploring a Faster Synthesis Technique J. Org. Chem. (IF 3.3) Pub Date : 2025-05-23
Aleksandra Helbik-Maciejewska, Agata Gitlin-Domagalska, Mladena Glavaš, Natalia Ptaszyńska, Dawid Dębowski, Anna Łęgowska, Krzysztof Rolka -
Gold-Catalyzed Conia-Ene Cyclization/Aza-Michael Addition Cascades: Access to Indolinylazepinone PNPs with Anticancer Activity J. Org. Chem. (IF 3.3) Pub Date : 2025-05-23
Xu Ling, Jinjie Wang, Yao Chen, Peirui Zhao, Dan Ni, Yue Wei, Shenyou Nie, Yi He
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