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Acrolein triftosylhydrazone: a versatile vinylcarbene reagent Org. Chem. Front. (IF 4.6) Pub Date : 2025-05-31
Ying Gan, Jin Zhang, Karunanidhi Murali, Yongquan Ning, Yong Wu, Jacek Mlynarski, Zhaohong Liu -
NCI-driven regioselectivity and enantioreversal in chiral phosphoric acid-catalyzed arylamine functionalization Org. Chem. Front. (IF 4.6) Pub Date : 2025-06-02
Zi-Hao Li, Abing Duan, Shu-Yu Zhang -
Cobalt-catalyzed enantioselective radical hydroamination of alkenes with N-fluorobenzenesulfonimides: theoretical insight of enantio-determining SN2-like reductive elimination Org. Chem. Front. (IF 4.6) Pub Date : 2025-05-28
Yu-Jie Liang, Bo Zhu, Ya-Bin Jiang, Wei Guan -
Dynamic supramolecular nanosheet structures formed by aromatic amphiphiles and their functions Org. Chem. Front. (IF 4.6) Pub Date : 2025-05-28
Yanqiu Wang, Myongsoo Lee -
Chelation-controlled stereospecific ring-opening arylation of α-aminoaryl-tethered alkylidenecyclopropanes: stereoselective synthesis of polysubstituted conjugated dienes Org. Chem. Front. (IF 4.6) Pub Date : 2025-05-23
Miao-Miao Ji, Ying Tang, Wen-Mei Luo, Yong-Yu He, Ai-Jun Ma, Jin-Bao Peng -
1,2,3-Trifunctionalization of α,α-disubstituted vinyl aldehydes with concomitant radical 1,2-migration of formyl group Org. Chem. Front. (IF 4.6) Pub Date : 2025-05-28
Xiong Yang, Jinmin Luo, Ji Li, Yao Yuan, Gangguo Zhu -
A photocatalytic electron-rich acceptor-involved EDA complexes for Markovnikov addition of alkynes with N-sulfonyl-azoles Org. Chem. Front. (IF 4.6) Pub Date : 2025-05-27
Jinhua Liu, Tang Xiao, Weixiong Chen, Zongjing Hu, Yun Zhao, Shunying Liu -
Photoinduced β-fragmentation for efficient pyridine alkylation via N-alkoxypyridinium salts Org. Chem. Front. (IF 4.6) Pub Date : 2025-05-23
Heng Liu, Fangrui Wu, Zhidong Wan, Changhai Yue, Changsheng Wang, Chengkou Liu, Yuguang Li, Zheng Fang, Hong Qin, Zhao Yang -
α-Sulfonylated ketazine synthesis from vinyl azides and sodium sulfinates using CAN: radical C–S/N–N coupling cascade as a key reaction pathway Org. Chem. Front. (IF 4.6) Pub Date : 2025-05-19
Mikhail M. Doronin, Alexander S. Klikushin, Olga M. Mulina, Michael G. Medvedev, Vera A. Vil’, Liang-Nian He, Alexander O. Terent'ev -
Recent progress in selective functionalization of diols via organocatalysis Org. Chem. Front. (IF 4.6) Pub Date : 2025-05-23
Liaba Niaz, Sojeong Bang, Jeonghyo Lee -
2-Pyridone-enabled manganese-catalyzed ortho-selective deuteration of aromatic amides with D2O Org. Chem. Front. (IF 4.6) Pub Date : 2025-05-19
Tao Qian, Zhi-Jiang Jiang, Jinfeng Zheng, Jia Chen, Zhanghua Gao, Jian-Fei Bai -
A formal vinylogous Schmidt reaction: nitrogen insertion of para-quinone methides Org. Chem. Front. (IF 4.6) Pub Date : 2025-05-20
Bo Wang, Chen Zhu, Yanhao Dong, Chen Kong, Hanxiao Zhu, Tiandi Ding, Guoyue Wei, Yatong Yang, Xin Zhao, Magnus Rueping, Qingqiang Yao, Kun Zhao, Yan Li, Ying Zhi -
BF3-enabled unusual (3 + 2) cycloaddition of bicyclobutanes with aldimine ester: access to 2-azabicyclo[2.1.1]hexanes Org. Chem. Front. (IF 4.6) Pub Date : 2025-05-21
Qin Jiang, Jianyang Dong, Dejiang Yu, Fang Lei, Ting Li, Tengfei Kang, Juan Fan, Huaming Sun, Dong Xue -
Selective separation of meta- and para-cresol using nonporous adaptive crystals of perpropoxylated pillar[5]arene Org. Chem. Front. (IF 4.6) Pub Date : 2025-05-15
Hongyan Zhang, Ming Li, Li Shao, Haozhong Liang, Bin Hua, Niveen M. Khashab, Feihe Huang -
Modular access to functionalized azetidines via electrophilic azetidinylation Org. Chem. Front. (IF 4.6) Pub Date : 2025-05-15
Dayu Tian, Guang Chen, Xian Xiao, Xiaocheng Wang, Hai-Jun Zhang -
Palladium-catalyzed intramolecular redox-relay Heck cyclization: access to heterocycles bearing all-carbon quaternary centers Org. Chem. Front. (IF 4.6) Pub Date : 2025-05-19
Linjun Qi, Rongjing He, Xiaofeng Tong, Shuling Yu -
Pyrrolyl-radical-based di-/tri-functionalization of alkenes using sulfonyl pyrroles via radical/radical cross-coupling Org. Chem. Front. (IF 4.6) Pub Date : 2025-05-15
Jia-Xuan Luo, Ze Zhuang, Yu-Zhang Huang, Xiaohui Kang, Yong Luo -
Cascade cyclization/fluoromethylthiolation of alkynes, unsaturated α-bromocarbonyls and PhSO2SRF Org. Chem. Front. (IF 4.6) Pub Date : 2025-05-14
Cui Zhang, Yun-Tao Shen, Ning-Xin Xia, Xin-Song Zhou, Li-Bo Yang, Jia Hu, Ya-Min Li -
Brønsted acid enabled metal-free remote oxygenation and amidation of unstrained C–C bonds via 1,4-heteroaryl migration chaperoned radical-polar crossover Org. Chem. Front. (IF 4.6) Pub Date : 2025-05-14
Xiaofei Xie, Yun Shi, Yukun Li, Jinge Gui, Yingguang Zhu, Kang Chen -
Active electropositive α-chlorine: trichloroacetonitrile as an electrophilic chlorination reagent Org. Chem. Front. (IF 4.6) Pub Date : 2025-05-14
Bingxing Zhou, Lei Bai, Changming Xu -
Rhodium-catalyzed one-pot tandem reductive amination/asymmetric transfer hydrogenation of quinoxaline-2-carbaldehydes and anilines for the efficient synthesis of chiral vicinal diamines Org. Chem. Front. (IF 4.6) Pub Date : 2025-05-13
Ji Yang, Zhenni He, Zhen Yao, Wei Huang, Siwen Meng, Lijin Xu, Qing-Hua Fan -
Organo-mediator enabled electrochemical 1,4-aryl migration of N-aryl-2-iodobenzamides/N-sulfonyl-2-iodoanilines to access biaryls Org. Chem. Front. (IF 4.6) Pub Date : 2025-05-13
Xiao-Qing Xie, Li-Tong Xiao, Wei Zhou, Yanli Wu, Haixin Ding, Ruchun Yang, Xian-Rong Song, Mu-Jia Luo, Qiang Xiao -
Reagent-controlled selective synthesis of sulfinamides and sulfoximines from tert-butanesulfinamide Org. Chem. Front. (IF 4.6) Pub Date : 2025-05-13
Wenbo Zhang, Yanhua Ouyang, Xi Zou, Bing Gao -
Photocatalytic anti-Markovnikov hydroalkylation of 2-aryl enamides via 1,2-hydrogen atom transfer of amidyl radicals Org. Chem. Front. (IF 4.6) Pub Date : 2025-05-12
Chengli Xiang, Lingli Liu, Changduo Pan, Jin-Tao Yu -
Photoinduced direct C–H cyanoalkylation of azauracils via electron donor–acceptor complex activation Org. Chem. Front. (IF 4.6) Pub Date : 2025-05-12
Zhi-Qiang Zhu, Xiao-Long Huang, Xi Yang, Qian-Qian Xu, Huo-Yu Rao, Zhen-Zhen Xu, Zong-Bo Xie, Zhang-Gao Le -
Selective α-Me–C(sp3)–H borylation of methyl sulfides controlled by substrate–ligand electrostatic interaction Org. Chem. Front. (IF 4.6) Pub Date : 2025-05-12
Rui-Mu Yu, Jin-Ping Li, Sumire Tobe, Shunsuke Yabu, Kanami Sugiayama, Li-Sheng Wang, Hirofumi Sato, Masahiro Higashi, Yoichiro Kuninobu, Hong-Liang Li -
Palladium-catalyzed site-selective C–H polyfluoroarylation of arenes via aryl thianthrenium salts Org. Chem. Front. (IF 4.6) Pub Date : 2025-05-07
Chen Chen, Jin-Ping Liu, Xin-Yu Hu, Zi-Yi Wang, Xiao-Xu Zhang, Jia-Hui Song, Yan-Ping Zhu, Chunjie Ni, Bolin Zhu -
Fluorine-containing macrocyclic peptides and peptidomimetics Org. Chem. Front. (IF 4.6) Pub Date : 2025-05-06
Neshat Rozatian, Stefan Roesner -
Beyond HAT: harnessing TBADT for photocatalyzed Giese-type C(sp3)–C(sp3) bond formation through reductive decarboxylation Org. Chem. Front. (IF 4.6) Pub Date : 2025-05-03
Matteo Leone, Dalila Arnaldi, Maurizio Fagnoni -
Copper-catalyzed Cloke–Wilson rearrangement for the synthesis of dihydrofurans containing tetrasubstituted carbon atoms Org. Chem. Front. (IF 4.6) Pub Date : 2025-05-08
Qinqin Cui, Shouang Lan, Xiang Lei, Chao Xu, Chunyun Jiang, Lili Zhao, Liyuan Zhou, Jinggong Liu, Cheng-Zhi Gu, Shuang Yang, Xinqiang Fang -
Rh(I)-catalyzed [4 + 2]-annulation of furan-fused cyclobutanones with alkynes and synthetic applications Org. Chem. Front. (IF 4.6) Pub Date : 2025-05-08
Lixin Qian, Jingjing Huang, Kemiao Hong, Xinyu Jiang, Mengting Liu, Gang Chen, Dorota Gryko, Xinfang Xu -
Catalyst-controlled 5-exo and 6-endo cyclization: regiodivergent access to indolinones and dihydroquinolinones Org. Chem. Front. (IF 4.6) Pub Date : 2025-05-07
Xianzhou Zheng, Youzhi Xu, Genping Huang, Weiming Yuan -
Cu-catalyzed regiodivergent and stereoselective silylation of 2,3-disubstituted 1,3-dienes Org. Chem. Front. (IF 4.6) Pub Date : 2025-05-07
Ziwei Luo, Hao Zeng, Junyang Cen, Ze Li, Guo-Qiao Lai, Pinglu Zhang -
Access to ester-substituted γ-butyrolactones via photocatalyzed alkoxycarbonylation/lactonization of alkenoic acids Org. Chem. Front. (IF 4.6) Pub Date : 2025-05-07
Yuping Xiong, Ping Liang, Wenlin Xie, Jian-Qiang Chen, Jie Wu -
Cs2AgBiBr6-photocatalyzed trifluoromethylation: insights into structural changes and applications in drug modification Org. Chem. Front. (IF 4.6) Pub Date : 2025-05-07
Debin Yang, Yalin Guo, Yuanzhe Li, Bo Hu, Bing Yu, Qingchuan Duan -
Design and synthetic utility of new HAT organocatalysts derived from commercially available diamines Org. Chem. Front. (IF 4.6) Pub Date : 2025-05-06
JingWen Jia, Terumasa Kato, Keiji Maruoka -
Synergistic catalytic allenylic alkylation for stereodivergent construction of allenes bearing 1,3-axial and central chirality Org. Chem. Front. (IF 4.6) Pub Date : 2025-05-05
Min Chen, Yuzhen Li, Jun He, Lili Lin, Liang-Wen Feng, Xiaohua Liu -
Mechanistic insights into ligand-controlled diastereoselectivity in iridium-catalyzed stereoselective coupling of allylic ethers and alkynes: a DFT perspective Org. Chem. Front. (IF 4.6) Pub Date : 2025-05-03
Manzhu Zhao, Lihan Zhu, Qian Zhang, Jingping Zhang -
Enantioselective construction of cycloalkyl amines via nickel-catalysed alkene desymmetrization Org. Chem. Front. (IF 4.6) Pub Date : 2025-04-29
Ludi Li, Bo Chen, Wenxu Cao, G. V. Surendra Babu, Weike Liao, Pengli Zhang, Guoqin Xia -
Synthesis of 8-membered trifluoromethyl benzoxazocines via a Pd-catalyzed ring-expansion reaction of trifluoromethyl benzoxazinones with 2-methylidenetrimethylene carbonate and mechanistic investigations Org. Chem. Front. (IF 4.6) Pub Date : 2025-04-28
Bo Yang, Peng-Fei Sun, Xue Ma, Zhouyang Long, Li-Ming Zhao -
meta-Selective thiofluoroalkylation of substituted pyridines via Zincke imines Org. Chem. Front. (IF 4.6) Pub Date : 2025-04-25
Will C. Hartley, Arnau Huerta, Júlia C. Negredo, Omar Boutureira -
Copper-catalyzed aryl ortho-C–H thiolation of aldehydes via a transient directing group strategy Org. Chem. Front. (IF 4.6) Pub Date : 2025-04-29
Mingshun Mei, Dongsheng Yi, Fanyi Meng, Junhao Tang, Yanghui Zhang -
Chiral phosphoric acid catalyzed asymmetric synthesis of C–N axially chiral uracils with antitumor activity through kinetic resolution strategy Org. Chem. Front. (IF 4.6) Pub Date : 2025-04-24
Jiawei Xu, Haisong Xu, Yunyi Xu, Zhongqi Peng, Wei Zhang, Xin Li -
Tetraphenylethylene or naphthalimide-functionalized dendritic carbazole AIEgens: self-assembly visualization, three disparate force-triggered fluorescence responses, and advanced anticounterfeiting applications Org. Chem. Front. (IF 4.6) Pub Date : 2025-04-29
Yijie Zou, Zhao Chen, Fei Zhao, Ya Yin, Kaixin He, Xingru Liang, Hai-feng He, Zhijian Li, Sheng Hua Liu -
Mechanistic insights into Ni–Al co-catalyzed alkyne carbophosphination enabled by C–P bond activation Org. Chem. Front. (IF 4.6) Pub Date : 2025-04-25
Congcong Huang, Yishi Li, Juan Li -
Palladium-catalyzed double strain-release (3 + 3) cycloaddition for the synthesis of vinylbicyclo[3.1.1]heptanes Org. Chem. Front. (IF 4.6) Pub Date : 2025-04-24
Xin-Yu Gao, Yuanjiu Xiao, Xuan Zhan, Yu-Jie Li, Kun-Ju Wang, Jian-Jun Feng -
Total synthesis and stereochemical assignment of cubensci acid Org. Chem. Front. (IF 4.6) Pub Date : 2025-04-23
Yangyang Jiang, Junyang Liu, Tao Ye -
Enantioselective and diastereodivergent construction of oxindole–pyrazolone conjugates bearing an alkenyl substituted quaternary chlorinated stereogenic centre Org. Chem. Front. (IF 4.6) Pub Date : 2025-04-28
Jiapei Chen, Xusheng Duan, Mengyuan Wu, Guishun Bai, Jianwei Chen, Xuanrong Sun, Jean Rodriguez, Damien Bonne, Hong Wang, Xiaoze Bao -
Multicomponent synthesis of unsymmetrical 1,2-diamines via photo-induced carbonyl alkylative amination Org. Chem. Front. (IF 4.6) Pub Date : 2025-04-28
Zhuohua Li, Wenjie Yan, Xiao Zhou, Chao Yang, Lin Guo, Wujiong Xia -
Copper-catalyzed aerobic oxidation of aldehydes to carboxylic acids Org. Chem. Front. (IF 4.6) Pub Date : 2025-04-26
Yankai Huang, Sheng Jiang, Zhengnan Zhou, Yibo Yu, Hui Qian, Shengming Ma -
Regioselective C–H alkynylation with haloalkynes enabled by nitrogen functionalities via Rh catalysis Org. Chem. Front. (IF 4.6) Pub Date : 2025-04-26
Qiaoya Zhang, Bifu Liu, Ci Chen, Yinling Li, Kejun Feng, Sheng Hu, Yang Gao, Yanping Huo, Qian Chen, Xianwei Li -
1,2 Wagner–Meerwein shift in aza-Nazarov cyclization: Bi(III)-catalyzed substrate-dependent divergent synthesis of highly substituted pyrroles and indenes Org. Chem. Front. (IF 4.6) Pub Date : 2025-04-26
Deepak Datta Gaonkar, Shon Gangai, Krishna Mhaske, Rishikesh Narayan -
Conformational preference of N-difluoromethylated amides: contributions of hydrogen-bonding, steric, and stereoelectronic effects Org. Chem. Front. (IF 4.6) Pub Date : 2025-04-25
Ryu Yamasaki, Ami Tashiro, Chisaki Sato, Ai Ito, Iwao Okamoto -
A cascade Markovnikov addition/Lewis acid-catalyzed rearrangement of methyleneaziridines and carboxylic acids: continuous-flow synthesis of α-amidoketones Org. Chem. Front. (IF 4.6) Pub Date : 2025-04-25
Bin Pan, Hao-Tian Sun, Feng Li, Qing-Bao Zhang, Shan-Shan Zhang, Jia-Hao Wang, Meng-Rui Xu, Jing-Tian Ge, Zi-Qing Hu, Shang Lv, Guo-Fu Huang, Li-Juan Feng -
Bis-Fischer indole[3,2-b]carbazole modification of [10]cycloparaphenylenes: tuning optical properties through rigid substitution Org. Chem. Front. (IF 4.6) Pub Date : 2025-04-24
Wanchun Duan, Dongming Chen, Dang Zheng, Shidong He, Wanqun Hu, Lvyuan Hao, Xin Xu -
Acidic pH-modulated photoswitching of sulfur-bridged seven-membered cyclic azopyridines Org. Chem. Front. (IF 4.6) Pub Date : 2025-04-24
Fengying Lan, Cefei Zhang, Zhihao Liu, Sitong Li, Jinmeng Yan, Xiaohu Zhao, Changwei Hu, Zhishan Su, Pengchi Deng, Zhipeng Yu -
Enantioselective synthesis of chiral seven-membered rings via Rh-catalyzed 1,4-addition of arylboronic acids to enones Org. Chem. Front. (IF 4.6) Pub Date : 2025-04-23
Hao-Ran Wang, Wen-Guang Zhou, Li-Wen Zhan, Long-Long Xi, Ren-Rong Liu -
Electrochemical carboxylation of α-fluoroalkyl cyclopropane with CO2 to mono- or difluoropentenoic acid Org. Chem. Front. (IF 4.6) Pub Date : 2025-04-23
Nan Feng, Mengmeng Jiang, Huimin Wang, Yuqing Zhong, Ying Sun, Deyong Yang, Feng Zhou -
A general protocol for efficient construction of perfluoro-tert-butyl alkynes with (perfluoro-tert-butyl)propiolic acid Org. Chem. Front. (IF 4.6) Pub Date : 2025-04-23
Zhiqiang Wei, Guangxing Gu, Wei Zhang, Yanchuan Zhao, Jinbo Hu -
Bifunctional iron-mediated multicomponent Markovnikov-selective radical hydrothiolation of alkenes Org. Chem. Front. (IF 4.6) Pub Date : 2025-04-22
Yi-Nuo Wang, Hongyu Jia, Lan Yao, Yu Chen, Han-Le Liu, Fengbing Liang, Dexin Feng, Da-Zhen Xu
更新日期：2025-05-08
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