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Structural anchoring of highly reactive CBH− for high-performance hypergolic coordination polymers with excellent thermal stability Inorg. Chem. Front. (IF 6.1) Pub Date : 2025-06-03
Qin Wang, Meng Cui, Pin-Hao Wei, Long-Chuan Li, Ning-Ning Zhang, Fei Tan, Fa-Kun Zheng, Jian-Gang Xu, Guo-Cong Guo -
Facilely synthesized crosslinked gel polymer electrolytes for high-performance quasi-solid-state rechargeable magnesium batteries Inorg. Chem. Front. (IF 6.1) Pub Date : 2025-06-02
Yukun Sun, Qinnan Zhou, Kaiwen Zheng, Feng Xiong, Yan Chen, Eslam Sheha, Jun Yang, Jiulin Wang, Yanna NuLi -
Thermal decomposition of neptunyl ammonium nitrate: mechanistic insights and structural characterization of the Np2O5 intermediate phase Inorg. Chem. Front. (IF 6.1) Pub Date : 2025-05-22
Kathryn M. Lawson, Tyler L. Spano, Jordan M. Roach, Connor J. Parker, Sara B. Isbill, Andrew Miskowiec -
pH-Modulated activation of a pendant amine leading to rapid electrocatalytic H2 production by a molecular copper complex in acidic water Inorg. Chem. Front. (IF 6.1) Pub Date : 2025-05-24
Naseer Ahmed Shah, Thinles Dolkar, Suhana Karim, Jumana Ishrat, Chandan Das, Srewashi Das, Aritro Sinha Roy, Kalishankar Bhattacharyya, Arnab Dutta -
(1,4)-Cycloaddition and C–X bond activation reactions of monovalent group 13 diyls Inorg. Chem. Front. (IF 6.1) Pub Date : 2025-05-19
Hanns Micha Weinert, Pratima Dhawan, Timo Freese, Christoph Wölper, Stephan Schulz -
Core–shell Ru/NiOx@graphene composite aerogels as efficient bifunctional electrocatalysts for overall water splitting Inorg. Chem. Front. (IF 6.1) Pub Date : 2025-05-22
Jiangcheng Zhang, Hu Yao, Xiayu Wang, Xin Yu, Qiuhan Cao, Xiaoyi Dong, Xiaohui Guo -
Kinetics enhancement of hierarchical hollow boride microspheres for double-high aqueous Zn-based batteries Inorg. Chem. Front. (IF 6.1) Pub Date : 2025-05-21
Shiyu Gu, Yaqi Wu, Liyuan Liu, Yang Li, Zihan Yang, Xiaodan Xia, Jinling Zhao, Qingliang Lv, Dehong Chen, Zhenyu Xiao -
Synergistic electrolyte engineering with TEABH4 additive: achieving oriented deposition and ultralong cycling in magnesium metal batteries Inorg. Chem. Front. (IF 6.1) Pub Date : 2025-05-20
Qi Sun, Shaohua Luo, Wei Zhao, Xin Yan, Rui Huang, Yicheng Lin, Qiuyue Liu, Shengxue Yan, Xiaoping Lin -
Boosting the growth kinetics of extra-large-pore zeolite ZEO-1 Inorg. Chem. Front. (IF 6.1) Pub Date : 2025-05-20
Haijun Yu, Wenjing Zhang, Yiqing Sun, Guangying Fu, Doudou Cai, Nourrdine Chaouati, Ludovic Pinard, Mohammad Fahda, Feng Shao, Peng Lu, Valentin Valtchev -
Role and advances in nonmetal doping of electrocatalysts for the hydrogen evolution reaction: a review Inorg. Chem. Front. (IF 6.1) Pub Date : 2025-05-19
Shenyue Xu, Chenxi Liu, Zefeng Teng, Fahao Sun, Jingqi Chi, Xiaobin Liu, Jianping Lai, Fusheng Liu, Lei Wang -
Coordination-induced in situ confinement of small-sized Ag nanoparticles on ultrathin C3N4 with strong metal–support interaction for enhanced selective CO2 photoreduction Inorg. Chem. Front. (IF 6.1) Pub Date : 2025-05-19
Qin Zhang, Jiancong Liu, Dongxu Wang, Chengxu Jin, Li Fang, Xingyu Li, Yingjie Jiang, Xin Wang, Chungui Tian -
Band alignment-driven space charge remodeling in NiFe LDH@CoOx-CNF heterojunction for efficient alkaline oxygen evolution Inorg. Chem. Front. (IF 6.1) Pub Date : 2025-05-16
Yuancong Luo, Jingjing Li, Yihui Shen, Huicheng Ge, Lingli Cheng, Zhen Li, Zheng Jiao -
Phosphoric acid passivation layer-induced sacrificial template effect for constructing S/P-modified self-supported NiFe catalysts with enhanced OER performance Inorg. Chem. Front. (IF 6.1) Pub Date : 2025-05-15
Rui Jian, Jie Wang, Pan Wang, Tiandong Qiu, Junjie Feng, Xiangyu He, Chuncheng Li, Zhichao Wang, Yufeng Zhang, Lianxin Gong, Luming Li, Hongmei Li, Si Chen, Yachao Zhu, Jie Deng -
Four-in-one multifunctional iron(III) complex for cancer theranostics: unique integration of targeted delivery, photodynamic therapy, and dual imaging modalities Inorg. Chem. Front. (IF 6.1) Pub Date : 2025-05-14
Tukki Sarkar, Serena Rizzuti, Isorchand Chongtham, Rajesh Kushwaha, Arnab Bhattacharyya, Samya Banerjee, Eliana Gianolio, Akhtar Hussain -
Magneto-chiral dichroism in a chiral twistacene ytterbium(III) one-dimensional assembly of single-molecule magnets Inorg. Chem. Front. (IF 6.1) Pub Date : 2025-05-08
Israa Shioukhi, Langit Cahya Adi, Vincent Dorcet, Olivier Cador, Geert L. J. A. Rikken, Boris Le Guennic, Jeanne Crassous, Cyrille Train, Fabrice Pointillart, Matteo Atzori, Ori Gidron -
Metal–coumarin derivatives as promising photosensitizers: unlocking their cancer phototherapy potential Inorg. Chem. Front. (IF 6.1) Pub Date : 2025-05-08
Gloria Vigueras, Eduardo Izquierdo-García, Elena de la Torre-Rubio, Diego Abad-Montero, Maria Dolores Santana, Vicente Marchán, José Ruiz -
SI-PPC-induced modulation of heparin/heparanase binding affinity: a steered molecular dynamics approach Inorg. Chem. Front. (IF 6.1) Pub Date : 2025-05-12
Frederico Henrique do Carmo Ferreira, Nicholas P. Farrell, Luiz Antônio Sodré Costa -
Exploring the potential of two-dimensional bismuth–copper hybrid double perovskites for memristor applications Inorg. Chem. Front. (IF 6.1) Pub Date : 2025-05-12
Mohamed Saber Lassoued, Kun Wang, Faizan Ahmad, Bai Sun, Yan-Zhen Zheng -
Metal selection tactic in a nitronyl nitroxide biradical-3d–4f macrocycle for boosting photothermal conversion and the application of solar-driven water evaporation Inorg. Chem. Front. (IF 6.1) Pub Date : 2025-05-12
Hongdao Li, Chaoyi Jin, Lu Xi, Lifeng Ding, Jing Han, Pei Jing -
Structural variations in the trans-carboxylate/chlorido axis that impact the mode of action of Pt(II) complexes Inorg. Chem. Front. (IF 6.1) Pub Date : 2025-05-12
David Fabra, Theresa Mendrina, Ana I. Matesanz, Ángeles Medrano, Rastislav Pitek, Isabella Poetsch, Walter Berger, Petra Heffeter, Adoración G. Quiroga -
Regulating the band gap of ZnxCd1−xS in 3DOM CaTiO3 for high hydrogen evolution and gluconic acid selectivity Inorg. Chem. Front. (IF 6.1) Pub Date : 2025-05-12
Ting-Ting Shen, Jing Liu, Fang-Yuan Bai, Wei-Wei Xu, Xue Yong, Zhi-Rong Li, Jing-Ru Han, Jun Chen, Heng Zhao, Zhi-Yi Hu, Yu Li, Bao-Lian Su -
Selective aromatic halogenation by a manganese compound I model: a mimic of chloroperoxidase Inorg. Chem. Front. (IF 6.1) Pub Date : 2025-05-12
Lina Zhang, Steiny Russelisaac Premakumari, Maggie Ng, Jisheng Zhang, Yong-Min Lee, Shunichi Fukuzumi, Kyung-Bin Cho, Wonwoo Nam -
Enhanced electrocatalytic hydrogen evolution with bimetallic Ru/Pt nanoparticles supported on nitrogen-doped reduced graphene oxide Inorg. Chem. Front. (IF 6.1) Pub Date : 2025-05-12
Heting Hou, Christian Cerezo-Navarrete, Dídac A. Fenoll, Matilda Kraft, Carlo Marini, Luis Rodríguez-Santiago, Xavier Solans-Monfort, Luis M. Martínez-Prieto, Nuria Romero, Jordi García-Antón, Xavier Sala -
Enhancing room-temperature CO oxidation via encapsulation of bimetallic PtNi clusters within mesoporous silicate-1 catalysts Inorg. Chem. Front. (IF 6.1) Pub Date : 2025-05-10
Ronghua Cui, Siyuan Yang, Lifeng Zhang, Xing Chen, Langli Luo -
(CN4H7)2SO4·H2O: high-performance metal-free ultraviolet birefringent crystal with KBBF-like configuration Inorg. Chem. Front. (IF 6.1) Pub Date : 2025-05-09
Xia Hao, Sijing Xie, Ruijie Wang, Chensheng Lin, Lingli Wu, Guang Peng, Tao Yan, Ning Ye, Min Luo -
A tri-alkali/alkaline-earth metal fluorophosphate deep-ultraviolet birefringent crystal with coexisting PO3F and PO2F2 Inorg. Chem. Front. (IF 6.1) Pub Date : 2025-05-09
Tao Ouyang, Ji Qi, Yanqiang Li, Shanshan Chen, Weiqi Huang, Zhiyong Bai, Sangen Zhao, Junhua Luo -
Metal-doped polyoxometalates with dual ligands for efficient CO2 photoreduction Inorg. Chem. Front. (IF 6.1) Pub Date : 2025-05-08
Yu Lv, Ting Jin, Ji-Lei Wang, Jiu-Lin Zhou, Zhi-Ming Dong, Hua Mei, Yan Xu -
A three-in-one strategy enables improved kinetics in an LLZTO solid electrolyte for Li-CO2 batteries with high energy efficiency Inorg. Chem. Front. (IF 6.1) Pub Date : 2025-05-07
Zesen Gao, Shijie Yang, Yan Yang, Futing Sun, Tianshuo Zhang, Yunluo Wang, Tianrui Zhou, Lang Tao, Hucheng Song, Haijie Chen -
Profiting from light-induced metal-to-metal intramolecular electron transfer: towards highly efficient heterodinuclear photosensitizers for photodynamic therapy Inorg. Chem. Front. (IF 6.1) Pub Date : 2025-05-07
Juan Sanz-Villafruela, Lisa-Marie Servos, Nicolás Montesdeoca, José V. Cuevas-Vicario, Artur J. Moro, João C. Lima, Marta Martínez-Alonso, Gustavo Espino, Johannes Karges -
Photochemical [2 + 2] reaction-tuned spin-crossover cooperativity in an Fe(II)–Ag(I) bimetallic Hofmann-type framework Inorg. Chem. Front. (IF 6.1) Pub Date : 2025-05-07
Long-Fei Wang, Liang Wu, Guo-Zhang Huang, Si-Guo Wu, Ming-Liang Tong -
Dual-state heptanuclear metal cluster-based MOF materials: open metal site enhanced acetylene/ethylene separation and coordinated water-driven propylene/propane kinetics Inorg. Chem. Front. (IF 6.1) Pub Date : 2025-05-07
Rizhao Zhang, Yaqing Fan, Jin-peng Xue, Yuqiao Chai, Bao Li, Jia Li -
Synergistic interplay between oxygen-vacancy and S-scheme charge transfer dynamics in an LaFeO3/FeOOH heterojunction towards sono-assisted photo-Fenton antibiotic degradation and water splitting Inorg. Chem. Front. (IF 6.1) Pub Date : 2025-05-06
Anshumika Mishra, Newmoon Priyadarshini, Kulamani Parida -
A Janus binder favors interfacial protection and mechanical stabilization for Li-rich layered oxide cathodes Inorg. Chem. Front. (IF 6.1) Pub Date : 2025-05-06
Wenhua Cheng, Qingcui Liu, Huan Zhou, Fengjuan Chen, Yudai Huang, Anqiang Pan -
Structural engineering of MXene frameworks with abundant surface functionalities for enhanced lithium–sulfur battery electrochemistry Inorg. Chem. Front. (IF 6.1) Pub Date : 2025-05-06
Yongjie Ye, Sisi Liu, Yongqian He, Wanqi Zhang, Ying Chen, Mengqing Wang, Xuewen Peng, Caixiang Wang, Qin Tang, Yan Luo, Bing Wu, Hongbo Shu, Ruizhi Yu, Manfang Chen -
Active site reconstruction of a metal hydroxide/metal molybdate heterogeneous interface enhances electrochemical water oxidation Inorg. Chem. Front. (IF 6.1) Pub Date : 2025-05-06
Xuanyu Zhou, Junjun Zhang, Mengyuan Zhang, Xiaoqian Du, Weiwei Bao, Jie Han, Xiu Lin, Pengfei Zhang, Zhenghong Luo -
High-entropy alloys and oxides as catalysts for water-splitting: synthesis, characterization, applications and prospects Inorg. Chem. Front. (IF 6.1) Pub Date : 2025-05-06
Tong Wu, Xiaoyi Zhang, Ziyu Yang, Zhilin Chen, Yihao Long, Liang He, Changsong Dai, Jibing Chen, Hui Tang -
Tailoring the catalytic microenvironment of large-scale Cu foil with polyaniline to enhance CH4 selectivity in CO2 electroreduction Inorg. Chem. Front. (IF 6.1) Pub Date : 2025-05-04
Yu-Ting Wen, Wan-Feng Xiong, Duan-Hui Si, Hong-Fang Li, Rong Cao -
Mutual restriction-driven anomalous multistage piezochromic behavior in copper(I) thiocyanate/isoquinoline coordination polymers Inorg. Chem. Front. (IF 6.1) Pub Date : 2025-04-29
Zhenxing Yang, Chunguang Zhai, Jianqi Shang, Lingyan Dang, Yuchen Shang, Jiangya Xu, Yupu Zheng, Xiaolu Qi, Rui Shi, Mingguang Yao -
Reverse quantum wells in gradient-doped CdS for photocatalytic H2O2 production Inorg. Chem. Front. (IF 6.1) Pub Date : 2025-04-29
Xiaoying Bo, Caijie Yang, Bolun Li, Yikang Fan, Jiaoyan Li, Hengming Huang, Jiahui Kou, Chunhua Lu -
Synthesis and reactivity of a benzo-fused 1,2-diborete biradicaloid Inorg. Chem. Front. (IF 6.1) Pub Date : 2025-05-02
Alena Häfner, Lukas Endres, Merle Arrowsmith, Cornelius Mimh, Sonja Fuchs, Samuel Nees, Krzystof Radacki, Ivo Krummenacher, Rüdiger Bertermann, Felipe Fantuzzi, Holger Braunschweig -
High entropy sulfide nanoparticles as redox catalysts for lithium–sulfur batteries Inorg. Chem. Front. (IF 6.1) Pub Date : 2025-04-30
Yiqian Li, Yuehan Hao, Usman Ali, Mingxin Sui, Qi Zhang, Lingyu Zhang, Lu Li, Bingqiu Liu, Chungang Wang -
Highly stable and reversible birefringence switching triggered by thermally stimulated phase transition Inorg. Chem. Front. (IF 6.1) Pub Date : 2025-05-01
Cheng Chen, Yunjie Bai, Qi Shi, Mingye Han, Bingbing Zhang, Ying Wang -
Hierarchically porous zeolite featuring an alveolus-like microsphere for efficient oxidative desulfurization Inorg. Chem. Front. (IF 6.1) Pub Date : 2025-05-01
Xing-Yu Yue, Yuan-Yuan Wang, Shen Yu, Chun-Mu Guo, Zhan Liu, Yi-Long Wang, Zhi-Yi Hu, Yu Li, Li-Hua Chen, Bao-Lian Su -
Microwave quasi-solid-state-constructed low-content Pt on CeO2 with strong electronic interactions for efficient electrocatalytic acidic overall water splitting Inorg. Chem. Front. (IF 6.1) Pub Date : 2025-04-29
Jing Li, Qihao Wang, Ruotong Guo, Yingxia Zong, Jun Xing, Weiping Xiao, Guangrui Xu, Dehong Chen, Lei Wang, Zexing Wu -
Cumulative 2c–2e vs. 3c–2e π-back donations: conformation preferences in germylene gold(I) complexes Inorg. Chem. Front. (IF 6.1) Pub Date : 2025-04-24
Lifang Wu, Rong Zhang, Xinran Wang, Wenyao Zeng, Lanhui Zhang, Yining Gao, Jiyong Liu, Lingbing Kong, Jiaxin Chen, Liliang Wang -
Linker-cluster cooperativity in confinement of proline-functionalized Zr-based metal–organic frameworks and its effect on the organocatalytic aldol reaction Inorg. Chem. Front. (IF 6.1) Pub Date : 2025-04-29
Zarfishan Dilruba, Ardeshir D. Yeganeh, Sofia Kolin, Sadia Noor, Hassan Shatla, Carl Wieland, Bo-Hung Yu, Katrin Gugeler, Anna Zens, Johannes Kästner, Deven P. Estes, Kristyna Pluhackova, Simon Krause, Sabine Laschat -
Enhancing electrocatalytic hydrogen evolution efficiency: tuning catalyst support pore size to optimize hydrogen adsorption–desorption kinetics Inorg. Chem. Front. (IF 6.1) Pub Date : 2025-04-28
Yong Zhou, Bin Yang, Bing Li, Xiaoyang Liu -
Rapid response and wide-band regulation of an electrochromic device achieved by ultra-small V2O5 nanodots and a Zn2+/Li+ electrolyte Inorg. Chem. Front. (IF 6.1) Pub Date : 2025-04-28
Ling Wang, Bin Wang, Haizeng Li, Lixin Qiao -
Harnessing the dual role of DMSO in the synthesis of SbOCl·DMSO: an excellent nonlinear optical crystal with unique 1D spiral chain Inorg. Chem. Front. (IF 6.1) Pub Date : 2025-04-24
Xiande Peng, Xiangyuan Li, Yingzi Zhang, Xuehua Dong, Ling Huang, Liling Cao, Daojiang Gao, Guohong Zou -
Modulating optical properties through cation substitution: composition-property relationships in MI3MIIIP3O9N:Eu2+ (MI = Na, K; MIII = Al, Ga, In) Inorg. Chem. Front. (IF 6.1) Pub Date : 2025-04-23
Nakyung Lee, Justyna Zeler, Małgorzata Sójka, Eugeniusz Zych, Jakoah Brgoch -
Deep-ultraviolet nonlinear-optical crystals LiBePO4 and BeP2O6 synthesized by ionic potential modulation towards uniform arrangement of PO4 groups Inorg. Chem. Front. (IF 6.1) Pub Date : 2025-04-28
Xia Zhang, Jian-Qiang Shen, Hong-Xiao Lv, Peng-Hui Guo, Yi-Gang Chen, Chun-Li Hu, Xian-Ming Zhang -
A bifunctional antioxidant for concurrent enhancement of stability and zinc-ion storage properties of Ti3C2Tx Inorg. Chem. Front. (IF 6.1) Pub Date : 2025-04-26
Jie Wang, Guohao Li, Hailiang He, Xiaohui Li, Jiale Fan, Yingxinjie Wang, Xiuqiang Xie, Nan Zhang -
Temperature-dependent interfacial reactions between a sulfide argyrodite solid electrolyte and a lithium metal anode Inorg. Chem. Front. (IF 6.1) Pub Date : 2025-04-25
Ye-Eun Park, SeoungJae Kang, Taehyun Kim, Huijeong Oh, Kyungsu Kim, Woosuk Cho, Sangryun Kim -
Enhancement of the photoelectrochemical water splitting performance of hematite photoanodes via uniform Ti and gradient Ge co-doping Inorg. Chem. Front. (IF 6.1) Pub Date : 2025-04-25
Chunlian Hu, Junhao Wu, Congzhao Dong, Xiao Fang, Pengfei Feng, Bonan Li, Baochun Ma, Yong Ding -
Pushing boundaries in single molecule magnets: an ab initio perspective on harnessing higher oxidation states for unprecedented lanthanide SMM performance Inorg. Chem. Front. (IF 6.1) Pub Date : 2025-04-24
Tanu Sharma, Rajanikanta Rana, Abinash Swain, Gopalan Rajaraman -
Strong NIR electrochemiluminescence from lanthanide ions sensitized with a carbon-rich ruthenium chelate Inorg. Chem. Front. (IF 6.1) Pub Date : 2025-04-24
Jing Yu, Miaoxia Liu, Tuan-Anh Phan, Laurent Bouffier, Lucie Norel, Stephane Rigaut, Neso Sojic -
High capacitive performances obtained in sandwich structured Bi0.5Na0.5TiO3-based dielectric ceramics Inorg. Chem. Front. (IF 6.1) Pub Date : 2025-04-22
Tengyue Liu, Ben Jia, Jiaqi Wang, Yuliang Zhou, Peng Zheng, Wangfeng Bai, Qiaolan Fan, Liang Zheng, Yang Zhang -
High-efficiency metal selenide as an electrocatalyst in a separator for lithium–sulfur batteries Inorg. Chem. Front. (IF 6.1) Pub Date : 2025-04-23
Yujuan Hu, Bo Jin, Hui Liu -
Selective electrocatalytic reduction of carbon dioxide to methane using a guanidine-based metal–organic cage Inorg. Chem. Front. (IF 6.1) Pub Date : 2025-04-23
Ziang Zhang, Yang Yang, Jinfeng Wang, Xu Jing, Chunying Duan -
Atomically precise metal nanocluster sandwich heterojunction for robust and efficient photocatalytic CO2 reduction to methanol Inorg. Chem. Front. (IF 6.1) Pub Date : 2025-04-23
Rui Lu, Aimin Yao, Yali Dai, Haijiao Yin, Chengqi Li, Yuanxin Du, Manzhou Zhu